Hydroxyapatite increases the environmental safety of perovskite solar cells

Scientists at the University of Manchester, UK, have found a way to accelerate the uptake of solar technology by increasing the environmental safety of perovskite solar cells.

Unlike silicon solar cells, perovskite solar cells can be mass produced through roll-to-roll processing. Additionally, they are light and colourful, with the versatility to be used in non-traditional settings such as windows and contoured roofs. Until now, application has been impacted by potential environmental risks. Perovskite solar cells contain lead, a cumulative toxin, and if the cells get damaged, lead ions may leak.

Professor Brian Saunders and Dr David Lewis have devised a way to eliminate the lead release from broken cells. Using a bioinspired mineral called hydroxyapatite, a major constituent of human bone, they have created a ‘failsafe’ which captures the lead ions in an inorganic matrix. As a result, if cells are damaged, toxins are stored in an inert mineral, rather than released in the environment.

Dr David Lewis, Deputy Head of Department and Reader in Materials Chemistry, said: “We embarked on this research as we were committed to eliminating an environmental risk. That commitment has resulted in increasing both the sustainability and the efficiency of perovskite solar cells. We hope these dual outcomes will increase the viability for homes and businesses, worldwide, to host and use solar technology.”

The effects of adding hydroxyapatite

The Engineering and Physical Sciences Research Council (EPSRC)-funded project also found that through the addition of hydroxyapatite, the efficiency of perovskite solar cell increased to around 21%. This compares to around 18% efficiency for control cells with no added hydroxyapatite. An increased efficiency in panels means more energy can be generated at a lower cost.

The research team hope that the cells will bring forward the large-scale application of perovskite solar cell technology.

Professor Brian Saunders, Professor of Polymer and Colloid Chemistry at the School of Materials, The University of Manchester, said: “Up until now, the substantial lead component in perovskite solar cells has been a potential environmental concern. If the solar cells are damaged, for example by hail, the ions may leak.

By creating an in-device fail-safe system, we have devised a way to contain toxic ions in damaged perovskite cells. Through increasing the inherent safety of perovskite solar cells, we hope our research will provide a helping hand to the wider deployment of solar technology as we strive to achieve net zero CO2 emissions.”

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